Mechanical Performance of Heat-Polymerized PMMA Reinforced with 0.7 wt % Nanoparticles

An Evaluation of Tensile Strength, Flexural Stength, and Shore D Hardness

Auteurs-es

  • Ali Ehsan Kareem
  • Tameem Khuder Jassim
  • Nagham Bahjat Kamil mustansiriah
  • Samir Samier
  • Rawaa Ali Rahmat

DOI :

https://doi.org/10.5195/d3000.2026.1620

Mots-clés :

PMMA, Acrylic Resin, Dentin, Dental Materials

Résumé

This study's goal was to determine how adding 0.7 w t% aluminum oxide (Al2O3), copper oxide (CuO), and zinc oxide (ZnO) nanoparticles affected the mechanical characteristics of heat-cured poly (methyl methacrylate) (PMMA), particularly in terms of tensile strength, strain, flexural strength, and Shore D hardness. After heat-curing PMMA samples, they were divided into four groups: an unmodified PMMA group and three experimental groups that were reinforced with 0.7 wt% of Al2O3, CuO, or ZnO nanoparticles, respectively. Tensile strength, flexural strength, and Shore D hardness tests were used to determine mechanical properties. ANOVA was used to evaluate the differences between the groups. Every mechanical property that was evaluated showed a significant difference between the four groups (P < 0.001). Control group's highest stress whereas Al₂O₃ group's maximum stress value was significantly lower. Maximum stress values for CuO and ZnO groups were 56.32 ± 3.44 MPa and 71.59 ± 1.05 MPa, respectively. The mean maximum strain was similar for Control and CuO, lowest for Al2O3, and highest for ZnO. All three nanoparticle-reinforced groups showed an increase in flexural strength when compared to control group. When nanoparticles were added, Shore D hardness also rose to 80.70 ± 0.9. The mechanical performance of heat-polymerized PMMA was considerably altered by addition of 0.7 wt % nanoparticles. ZnO showed the best tensile response by producing highest maximum strain and sustaining maximum stress around control, and Al₂O₃ showed most gain in flexural strength and surface hardness. CuO improved flexural strength and hardness while producing an intermediate mechanical response. These results suggest that choosing the right nanoparticles is crucial in dental applications.

Références

1. Ahmed MA, Ebrahim MI. Effect of zirconium oxide nanoparticles on PMMA properties. World J Dent. 2021;12(3):191-6.

2. Shirkavand S, Moslehifard E. TiO₂ nanoparticles in acrylic resins. J Dent Res Dent Clin Dent Prospects. 2021;15(2):113-8.

3. Alqutaibi AY, Baik A, Almuzaini SA, Farghal AE, Alnazzawi AA, Borzangy S, Aboalrejal AN, AbdElaziz MH, Mahmoud II, Zafar MS. Polymeric Denture Base Materials: A Review. Polymers (Basel). 2023 Jul 31;15(15):3258.

4. Zhang R. Biofilm inhibition using AgNPs. Colloids Surf B Biointerfaces. 2020;190:110950.

5. Khan AS. Nanocomposites for dental applications. Nanomaterials (Basel). 2020;10(12):2500.

6. Kotian, R. (2020). Effect of titanium dioxide nanoparticle reinforcement on flexural strength of denture base resin: A systematic review and meta-analysis. Japanese Dental Science Review.

7. Aldwimi, I. M., Akil, H. M., Hamid, Z. A. A., & Alhareb, A. O. (2025). Properties of the Modified Polymethyl Methacrylate as Denture Base Materials: A Comprehensive Review. International Journal, 13(2), 32-59.

8. Alnamel, H. A., & Mudhaffer, M. The effect of Silicon di oxide Nano-Fillers reinforcement on some properties of heat cure polymethyl methacrylate denture base material. Journal of baghdad college of dentistry. 2014, 26(1), 32-36).

9. Craig R.G; John M. Powers; John C.W.(2004). “dental material properties and manipulation”, Eight edition ,2014 p.270-280.

10. ADA specification No.12 American dental associated specification no.12 for denture base polymer.Chicago;councilor dental material and device 1999.

11. International Organization for Standardization (ISO), Plastics Determination of Tensile Properties. International Organization for Standardization: Geneva, Switzerland, 527-1:2019.

12. International Organization for Standardization (ISO), Dentistry Base Polymers—Part 2: Orthodontic Base Polymers (ISO 20795-2:2013).

13. Mahmoudi Anzabi, R., Divband, B., Tukmachi, M. S., Vahedifar, S., Esmaeilzadeh, M., Yeganeh Sefidan, F., ... & Rafighi, A. Assessment of Physicochemical Properties, Cytotoxicity, Antimicrobial Activity, and Flexural Strength of Self‐Cured Acrylic Resin With Silver Nanoparticles on Delaminated Clay for Removable Appliances. International Journal of Dentistry,2025,(1), 7939455.

14. ADA (American Dental Association) Specification No. 12 Denture Base Polymers. Council on Scientific Affairs. 2002; Approval date: September 13.

15. IBM SPSS, I. (2009). PASW statistics for windows, version 18.0. Chicago: SPSS Inc.‏

16. Pourhajibagher M, Bahador A. Effects of incorporation of nanoparticles into dental acrylic resins on antimicrobial and physico-mechanical properties: A meta-analysis of in vitro studies. J Oral Biol Craniofac Res. 2022 Sep-Oct;12(5):557-568.

17. Galant K, Turosz N, Chęcińska K, Chęciński M, Cholewa-Kowalska K, Karwan S, Chlubek D, Sikora M. Silver Nanoparticles (AgNPs) Incorporation into Polymethyl Methacrylate (PMMA) for Dental Appliance Fabrication: A Systematic Review and Meta-Analysis of Mechanical Properties. Int J Mol Sci. 2024 Nov 25;25(23):12645.

18. Salahuddin N, El-Kemary M, Ibrahim E. Reinforcement of polymethyl methacrylate denture base resin with ZnO nanostructures. Int J Appl Ceram Technol. 2018; 15: 448-459.

19. Chobey AR, Seth J. Nanostructural reinforcement of heat-polymerized PMMA denture base resin using alumina nanoparticles: An in vitro evaluation of flexural behavior and surface topography. J. Sci. Adv. Dent. 2026;1(1):3-7.

20. Ozkan Ata S, Akay C, Mumcu E. The effects of metal nanoparticles incorporation on the mechanical properties of denture base acrylic resin. Eur Oral Res. 2023 Jan 9;57(1):36-40.

21. Cierech M, Osica I, Kolenda A, Wojnarowicz J, Szmigiel D, Łojkowski W, Kurzydłowski K, Ariga K, Mierzwińska-Nastalska E. Mechanical and Physicochemical Properties of Newly Formed ZnO-PMMA Nanocomposites for Denture Bases. Nanomaterials (Basel). 2018 May 6;8(5):305.

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Publié-e

2026-10-06

Numéro

Rubrique

Mechanisms of Oral Disease