Effect of Nanoparticles on the Mechanical Properties of Polymethyl Methacrylate Denture Base Material

Authors

  • Omar M. Faruq Abdlrahman Department of Prosthodontics, Ministry of Health
  • Farhad Wahid Rasool
  • Fahd Sudad Ikram

DOI:

https://doi.org/10.5195/d3000.2025.1069

Keywords:

PMMA, Nanoparticle reinforcement, Surface hardness, Zirconium dioxide (ZrO₂), Dental prosthesis materials

Abstract

Polymethylmethacrylate (PMMA) has been widely used as a denture base material due to its favorable properties but exhibits limitations in mechanical strength. This study investigated the effects of incorporating three different nanoparticles - zirconium dioxide (ZrO₂), silicon dioxide (SiO₂), and diamond nanoparticles (DNPs) at varying concentrations (0.5%, 1.0%, 2.5%, and 5.0%) on the mechanical properties of PMMA denture base material. The incorporation of nanoparticles demonstrated concentration-dependent effects on PMMA properties. ZrO₂ nanoparticles at 1.0% concentration showed optimal results with improved hardness (21.4 ± 0.8 VHN) while maintaining acceptable surface roughness. Higher concentrations (2.5% and 5.0%) led to increased surface roughness and decreased hardness across all nanoparticle types. Diamond nanoparticles exhibited the highest surface roughness (0.146 ± 0.017 μm) at 5.0% concentration, while SiO₂ showed moderate improvements in mechanical properties at lower concentrations. Surface morphology analysis revealed excellent particle dispersion at 0.5-1.0% concentrations, with significant agglomeration observed at higher concentrations. The study determines that 1.0% concentration is the optimum level to utilize for the addition of nanoparticles into PMMA denture base materials, wherein ZrO₂ nanoparticles show the optimum balance of enhanced material properties and preserved surface features. The findings show that precise control of particle concentration is required to achieve enhanced material properties without compromising surface integrity that will in turn translate to enhanced clinical performance of dental prostheses.

References

Baloš, S., Pilic B., Markovic D., Pavlicevic J., and Luzanin O. “Poly(methyl-methacrylate) Nanocomposites with Low Silica Addition.” *The Journal of Prosthetic Dentistry*, vol. 111, no. 4, 2014, pp. 327–34. https://doi.org/10.1016/j.prosdent.2013.06.021.

Gad, M. M., Al-Thobity, A. M., Rahoma, A., ArRejaie, A. S., and Al-Harbi, F. A. “Influence of Addition of Different Nanoparticles on the Surface Properties of Poly(methylmethacrylate) Denture Base Material.” *Journal of Prosthodontics*, vol. 29, no. 5, 2020, pp. 422–28. https://doi.org/10.1111/jopr.13168.

Ergun, G., Sahin, Z., and Ataol, A. S. “The Effects of Adding Various Ratios of Zirconium Oxide Nanoparticles to Poly(methyl Methacrylate) on Physical and Mechanical Properties.” *Journal of Oral Science,* vol. 60, no. 2, 2018, pp. 304–15. https://doi.org/10.2334/josnusd.17-0206.

Mangal, U., Kim, J., and Yoo, G. “Novel Poly(Methyl Methacrylate) Containing Nanodiamond to Improve the Mechanical Properties and Fungal Resistance.” *Materials,* vol. 12, no. 20, 2019, article no. 3438. https://doi.org/10.3390/ma12203438.

Moudhaffar, M., and Ns. I. N. S. “Evaluation of the Effect of Modified Nano-Fillers Addition on Some Properties of Heat Cured Acrylic Denture Base Material.” *Journal of Baghdad College of Dentistry,* vol. 23, no. 1, 2011, pp. 23–29.

Kaurani, A., Tomar, P., and Kaurani, M. “Effect of Addition of Titanium Oxide and Zirconium Oxide Nanoparticles on the Surface Roughness of Heat Cured Denture Base Resins: An In -Vitro Study.” Manuscript, 2021.

Nejatian, T., Johnson, A., and Van Noort, R. “Reinforcement of Denture Base Resin.” *Advances in Science and Technology,* vol. 49, 2006, pp. 124–130. https://doi.org/10.4028/www.scientific.net/AST.49.124.

Salman, A. D., Jani, G. H., and Fatalla, A. A. “Comparative Study of the Effect of Incorporating SiO₂ Nano-Particles on Properties of Poly Methyl Methacrylate Denture Bases.” *Biomedical & Pharmacology Journal,* vol. 10, no. 3, 2017, pp. 1499–1506. https://doi.org/10.13005/BPJ/1262.

Rashahmadi, S., Mosalman, S., and Hasanzadeh, R. “Improving the Mechanical Properties of Poly Methyl Methacrylate Nanocomposites for Dentistry Applications Reinforced with Different Nanoparticles.” *Polymer-Plastics Technology and Engineering,* vol. 56, no. 16, 2017, pp. 1730–40. https://doi.org/10.1080/03602559.2017.1289402.

Naguib, Ghada H., et al. “Influence of Inorganic Nanoparticles on Dental Materials’ Mechanical Properties. A Narrative Review.” *BMC Oral Health,* vol. 23, 2023, article no. 3652. https://doi.org/10.1186/s12903-023-03652-1.

Kaurani, A., Tomar, P., and Kaurani, M. “Effect of Addition of Titanium Oxide and Zirconium Oxide Nanoparticles on the Surface Roughness of Heat Cured Denture Base Resins: An In - Vitro Study.” Manuscript, 2021.

Zidan, S., Silikas, N., Alhotan, A., Haider, J., and Yates, J. “Investigating the Mechanical Properties of ZrO₂-Impregnated PMMA Nanocomposite for Denture-Based Applications.” *Materials,* vol. 12, no. 8, 2019, article no. 1344. https://doi.org/10.3390/ma12081344.

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Published

2025-11-10

Issue

Section

Mechanisms of Oral Disease